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Técnicas experimentales para caracterizar materiales fotoconductores

Experimental techniques to characterize photoconductive materials

 

Cristian Daniel Arambulo Almendariz. [1] &= amp; Luis Santiago Carrera Almendáriz. [2]

 

 

Recibido: 16-05-2021 / Revisado: 27-05-2021 /Acepta= do: 20-06-2021/ Publicado: 05-07-2021

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Abstract                                          DOI: https://doi.o= rg/10.33262/concienciadigital.v4i3.1793

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Introduction. Photoconductive materials are those that, when exposed to electromagnetic radiation, vary their electrical conductivity. I= ts applications are diverse and highly valuable in science and industry. Among= the experimental techniques used to characterize these materials are scanning electron microscopy, optical microscopy, ray diffraction, the tunneling eff= ect, among others. Objective. It presents a documentary review of the experimental techniques for the characterization of photoconductive materia= ls. Methodology. The methodology was qualitative, related to the review of scientific papers, articles and texts, which allowed establishing an approximate state of the = art in this field of study. Results. Among the relevant results, it was found that the characterization depends on the nature of the material and t= he source of electromagnetic radiation that is used to stimulate it, such as t= he intensity of the light, the frequency, the number of photons, among other properties. it is possible, with due caution, to use photoconductivity as a diagnostic tool in the study of new materials and electronic devices. Also,= it was observed that the majority of samples analyzed and classified reveal a tendency to increase photoconduction, in addition to the use of numerical methods to carry out virtual experiments assisted by computer simulations, whose usefulness lies in the corroboration of the results obtained. by the empirical and analytical route.=

Keywords: characterizati= on of materials, experimental techniques, photoconduction, conductivity, numer= ical methods.=

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Resumen

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Introducción. Los materiales fotoconductores, son aquellos que, al estar expuestos a la radiación electromagnética, varían su conductividad eléctrica. Sus aplicaci= ones son diversas y muy valiosas en las ciencias y la industria. Entre las técni= cas experimentales que se usan para la caracterización de estos materiales, se encuentran la microscopía electrónica de barrido, la microscopía óptica, la difracción de rayos, el efect= o tunelamiento, entre otras.  Objetivo. Presentar una revisión de tipo documen= tal, de las técnicas experimentales para la caracterización de materiales fotoconductores. Metodología. La metodología fue cualitativa, relacionada con la revisión de trabajos, artículos y textos científicos, que permitieron establecer un estado del arte aproximado, de este campo de estu= dio. Resultados. Dentro de los resultados más relevantes se encontró, que= la caracterización depende de la naturaleza del material y de la fuente de radiación electromagnética que se usa para estimularlo, como, la intensidad= de la luz, la frecuencia, el número de fotones, entre otras propiedades. Es posible, con la debida cautela, utilizar la fotoconductividad como herramie= nta de diagnóstico en el estudio de nuevos materiales y dispositivos electrónic= os. También, se pudo observar que la mayoría de muestras analizadas y clasifica= das revelan una tendencia al aumento de la fotoconducción<= /span>, además, del uso de métodos numéricos para la realización de experimentos virtuales asistidos por simulaciones computacionales, cuya utilidad radica = en la corroboración de los resultados obtenidos por la vía empírica y analític= a.

P= alabras claves: caracterización de materiales, técnicas experimentales, fotones, fotoconducción, conductividad, métodos numéricos.

 

Intro= ducción

La caracterización de materiales es una actividad = que usa métodos de la Física y de la Química Analítica para llevar a cabo el desarrollo de sus actividades. El conocimiento que se tiene de las clases de materiales en la actualidad es muy extenso, y su caracterización está somet= ida a diferentes fenómenos, entre ellos, la fotoconductividad, la cual, es la temática central de esta investigación.

En lo que respecta a la clasificación, existen tres grandes grupos: = los metales, los polímeros, y los cerámicos. Sin embargo, una clasificación más actualizada, presenta una lista más extensa que contiene materiales compues= tos, electrónicos, inteligentes, nanomateriales, con memoria de forma, piezoelectrónicos, microelectromecánicos, entre otros= .

Para los materiales mencionados, los experimentos muestran un incremento importante en los órde= nes de magnitud de comportamientos fotosensibles y fotoconductores de los compuestos, cuando se les hacía incidir radiación electromagnética, del ord= en de magnitud del espectro UV y visible. Entre los parámetros detectados con éxito, se encuentran: tiempo de vida, longitud de difusión, el producto tiempo de vida-movilidad, niveles de impurezas y nivel de Fermi, el cual es un paráme= tro mecánico cuántico.

También, se han encontrado evidencias significativas del aumento de la fotoconductividad, de micro cavidades de silicio poroso nanoestructurado. Al respecto Urreaga, Marín, Acquaroli, Comedi, Schmidt & <= span class=3DSpellE>Koropecki, (2008) seńalan: “se utilizó silicio poroso nanoestructurado para construir una   microcav= idad   óptica   que   permite   aumentar   la fotoconductancia debido al confinamie= nto del campo eléctrico dentro de la microcavidad.<= span style=3D'mso-spacerun:yes'>  El dispositivo está formado por una cap= a de espesor óptico igual a media longitud de onda separado por dos arreglos periódicos de capas que alternan su porosidad” (p. 113) <= /p>

En particular, en esta revisión documental, se persigue como objetivo general, conocer los referentes, métodos, resultados= y conclusiones acerca de las investigaciones, con el fin de poder realizar una clasificación de las diferentes técnicas para la caracterización de materia= les fotoconductores. Asimismo, la interrogante principal de esta investigación, está referida a lo siguiente: żQué técnicas de experimentación son las más usadas en la caracterización de materiales fotoconductores?

Metodología

En el presente artículo, se realiza una investigac= ión dentro del enfoque cualitativo, de tipo documental, acerca de las diferentes técnicas experimentales para caracterizar materiales fotoconductores. De la revisión realizada para llevar a cabo el proceso metodológico, se tomaron en cuenta, las de caracterización y revisión aproximada de las investigaciones= de cuarto y quinto nivel (trabajos de maestría y doctorado), y los artículos en revistas indexadas, haciendo hincapié en las particularidades de cada una, = así como sus potencialidades y debilidades experimentales y aplicativas. Tambié= n se tomó en cuenta la correspondencia de los resultados experimentales con los modelos analíticos y numéricos, además, se presentan otras técnicas de caracterización de los materiales, que seguramente serán de interés para el lector.

Los materiales generalmente se caracterizan tomand= o en cuenta sus propiedades físicas y químicas. Los métodos de caracterización de dividen en dos grandes grupos, clásico e instrumental. El método clásico a = su vez puede ser dividido en dos técnicas protocolares. La primera consiste en= la separación de los componentes que se pretenden analizar (estos componentes = se denominan analitos), por medio de la precipitación, extracción y destilació= n. La segunda, es la “formación”, que consiste en la reacción del analito con = un reactivo, con el fin de formar un producto determinado (Faraldos & Goberna, 2011, p.19).

Después de esta etapa, se procede a realizar un análisis cualitativo, donde se determinan tanto las propiedades físicas, co= mo las químicas del analito, entre ellas, el color, el punto de fusión, el pun= to ebullición, el olor, la solubilidad, la actividad óptica, el índice de refracción, entre otras.

Los métodos instrumentales, se pueden dividir en d= os grupos, el primero basado en técnicas cromatográficas de separación de alta eficacia para gases y líquidos. Este proceso puede reemplazar la separación de analitos. El segundo, consiste en el estudio de propiedades de la materia relacionadas con la emisión, absorción, dispersió= n, y difracción de radiación electromagnética (espectroscópicas). Sin embargo, o= tras propiedades, como la conductividad eléctrica y térmica, el potencial de electrodo, la proporción carga-masa, entre otras, pueden ser también inclui= das (Faraldos & Goberna, 2011, p.22).

Son muchas las técnicas que se han venido desarrollando y aplicando en este campo de estudios. El conocido diagrama d= e Propst, usado con frecuencia en Ciencias de los Mater= iales, representa esquemáticamente sus diferencias en función de las seńales de perturbación, y la respuesta del material. Estas están asociadas a los dist= intos fenómenos que ocurren en el proceso experimental: fotones, electrones, ione= s, partículas neutras, calor y efectos de campo (eléctrico, magnético, y electromagnético).

En los métodos de análisis espectroscópicos de seńales, como uno de los campos que mayor número de técnicas posee, por ejemplo, las seńales pueden ser de siete tipos y asociadas con la interacci= ón de partículas (Faraldos & Goberna, 2011, p.53). La que interesa a esta investigación, es aquella que usa foton= es como seńal de estímulo. 

En la caracterización de materiales semiconductores amorfos, a través de las técnicas basadas en la fotoconductividad, Kopprio (2019), presentó una investigac= ión que mostró las distintas técnicas de caracterización en estado estacionario= . El objetivo de la misma, era medir la conductividad del material, cuando era iluminado con luz de energía mayor a su banda prohibida (gap), tal que con = los resultados obtenidos se pudiera hacer una clasificación de materiales semiconductores para la aplicación en la industria de celdas fotovoltaicas = de alta eficiencia. Es importante mencionar, que está investigación presentó u= na innovación notoria, en cuanto a los formalismos matemáticos obtenidos, los cuales permitieron la correspondencia entre las mediciones de fotoconductiv= idad bajo determinadas condiciones experimentales, con la movilidad de deriva de= los fotoelectrones, la longitud de difusión ambipolar de los fotoelectrones, y el tiempo común de recombinación de pequeńa seńal , que a su vez se refleja en el SPV. La medición de  implica escalonar la longitud de onda de= la luz incidente y ajustar su intensidad después de cada paso para mantener un= SPV constante. Cada una corresponde con una profundidad de absorción específica=  en el semiconductor, y el valor de  se obtiene a través de la intersección d= e un gráfico de intensidad de luz versus profundidad de absorción. (Kronik y Shapira, 1999, p.6-7).

Comúnmente SPV se usa particularmente en materiale= s a granel, aunque se afirma que surgen inexactitudes cuando se usa en películas delgadas, siendo versátil, y configurable para medir la densidad del estado= de la superficie y las longitudes de separación de carga en materiales, como grupos moleculares y puntos cuánticos. También forma la base de una microsc= opía de potencial de superficie (microscopía de fuerza de sonda Kelvin) cuando se combina con un sistema AFM. La técnica en estabilizar la fuerza electrostát= ica entre la punta y el semiconductor, la cual se ajusta a cero mediante la aplicación de un potencial de polarización, cuyo valor se representa en fun= ción de la posición para producir un mapa de superficie (mapeo conforme).

Otra técnica, es la Recombinación Dependiente del Giro, está influenciada tanto por las propiedades del material como por parámetros externos. Una variable externa adicional, junto con la temperatu= ra y la intensidad de la luz, es proporcionada por la posibilidad de alterar la cinética de recombinación mediante la inversión de giro. Así, al iluminar u= na muestra fotoconductora y escanear en un sistema de resonancia de espín de electrones (ESR), la condición de resonancia puede detectarse como una disminución de la fotoconductividad.

La técnica TRMC, conocida como la Conductividad Microondas de Resolución Temporal, consiste en medir los cambios en la reflectividad de microondas de un fotoconductor cuando se crean portadores fotogenerados en exceso, por un breve destello de luz. La reflectividad es proporcional a la densidad del portador libre, lo que produce una desintegración transitoria en muchos órdenes de magnitud de tiempo similar = al método TPC (Pillai et al., 2= 019. p.1-10).

Savenije et al. (2020), para la técnica TRM, reportan: “nuestras mediciones de TRMC en las bicapas revelaron que los electrones en estados defectuosos cercanos al VB pueden ser excitad= os por fotones con una energía tan baja como 1,30 eV. Su excitación conduce a electrones libres en el CB que se someten a inyección de carga en el C60 produciendo una separación de carga de larga duración. Por el contrario, la excitación de MAPbI3 / Spiro-OMeTAD a 1,3 eV muestra una seńal que decae rápidamente, lo que implica que los agujeros están localizados y no pueden transferirse a través de la interfaz al Spiro-OMeTAD” (p.1)

La fotoconductividad persistente (PPC), es el fenó= meno en el que la respuesta del semiconductor puede persistir durante mucho tiem= po después de que se apaga la iluminación, estando asociada con defectos cristalinos. Se ha observado en muchos semiconductores, incluidos el silicio (Si), azufre, óxidos y calcogenuros (Vega, 2019 p.16)= .

Esta importante propiedad tiene implicaciones en u= na serie de aplicaciones optoelectrónicas, incluidas las células solares, los dispositivos regrabables y los fotodetectores. Entre estos materiales, el <= span class=3DSpellE>CdS ha sido ampliamente reconocido como un excelente = fotoconductor. Se realizó la sintetización de películas de CdS utilizando trietanolamina (TEA) como agente compl= ejante y tiourea como fuente de azufre. La fotosensibilidad informada, caracteriza= da por una relación de corriente de luz a oscuridad, alcanza 106 bajo iluminac= ión AM2 para muestras recién preparadas y 107 después de que estas muestras se hayan almacenado durante varias horas a 50 ° C (Ko et al., 2017)= .

La razón de este aumento permanece indeterminada, = pero se sugiere que se debe al oxígeno quimisorbido = en la superficie y los límites de los granos que sirven como centros de recombina= ción adicionales, lo cual es consistente con los hallazgos de Lee, Mun y JU (2021). El mismo grupo también logró películas con aproximadamente <= span style=3D'font-size:11.0pt;line-height:115%;font-family:"Calibri",sans-serif; mso-ascii-theme-font:minor-latin;mso-fareast-font-family:"Times New Roman"; mso-fareast-theme-font:minor-fareast;mso-hansi-theme-font:minor-latin; mso-bidi-font-family:"Times New Roman";mso-bidi-theme-font:minor-bidi; position:relative;top:5.5pt;mso-text-raise:-5.5pt;mso-ansi-language:ES; mso-fareast-language:ES;mso-bidi-language:AR-SA'>  de fotosensibilidad bajo luz AM1 y un ti= empo de descomposición de  utilizando el mismo método de síntesis anterior, pero variando ligeramente la relación entre la fuente de cadmio y azufre. A pesar de la cantidad de trabajo sobre el efecto PPC en CdS, nunca se ha estudiado sistemáticamente para conf= irmar la fuente de PPC o el mecanismo subyacente real.

La Espectroscopia Infrarroja permite el estudio de= las interacciones entre la materia y la radiación infrarroja, esta radiación corresponde a la zona- del espectro electromagnético que incluye las longit= udes de onda entre los  y (Faraldos & Goberna, 2011, p.139).

Mediante la espectroscopia IR es posible identific= ar especies químicas de la frecuencia a la que los diferentes grupos funcional= es presentan bandas de absorción en el espectro asociado. Además, la intensida= d de banda puede ser utilizada para obtener la concentración de cada compuesto e= n la muestra. Por último, al comparar los espectros IR de distintas muestras, se puede conocer si ambas poseen la misma composición (Faraldos & Goberna, 2011, p. 147).

La espectroscopía IR posee algunas ventajas importantes, como técnica analítica. Permite caracterizar muestras en cualq= uier estado de agregación, esto implica que se pueden realizar estudios en sustancias sólidas, liquidas o gaseosas. Esta es una técnica sencilla y ráp= ida, en la mayoría de situaciones se puede preparar la muestra, registrar el espectro y emitir un resultado en unos minutos y además con una alta sensibilidad (Faraldos & Goberna, 2011, p.160).

Cuando las moléculas son excitadas por la absorció= n de radiación UV-VIS, se presenta un fenómeno conocido como fluorescencia, este= es un proceso en el cual las moléculas de la muestra emiten energía en forma de fotones. La técnica usada para llevar a cabo este estudio es la Espectrosco= pia Ultravioleta Visible. Generalmente, esta transición se produce cuando se ex= cita el material de su estado electrónico fundamental. Una de las característica= s más vistosas del fenómeno es su sensibilidad inherente al mismo, que con frecue= ncia posee una magnitud mayor que en la espectroscopía de absorción (Peńa, 2011, p.38= ).

Sin embargo, estos métodos se aplican en menor cantidad que los de absorción, debido al número relativamente bajo de muest= ras que son capaces de fluorescer de forma apropiad= a. Por esta razón, en sus comienzos, la técnica únicamente era usada en el estudio= de sistemas biológicos. En la actualidad se ha ido implementando en otros tipo= s de sistemas, entre ellos los polímeros sintéticos. Esta técnica es una poderosa herramienta, altamente sensible y no destructiva, muy importante para conoc= er el comportamiento físico y químico de las macromoléculas. Puede ser implementado en varios niveles, desde una simple medida de la emisión en es= tado estacionario hasta llegar a intrincados estudios de resolución temporal (Peńa, 2011, p.35= ).

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Figura 1: Esquemática de los diferentes procesos fotofísicos que pueden tener lugar tras la
excitación inicial desde el estado.

Fuente: (Peńa, 2011, figura 2.5, p.36)

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De la investigación documental realizada se pudo encontrar que existen un conjunto de técnicas de caracterización de materia= les fotoconductores, que presentan similitudes y diferencias en cuanto a sus procesos y aplicaciones.

En el caso de la caracterización de semiconductore= s:<= /p>

1.&n= bsp;     La fotoconductividad de estado estacionario bajo una tasa de generación uniforme (SSPC), presenta que la estimulación de la fotocorriente en la muestra es favorable, pero presenta = la limitación de que sólo es aplicable a materiales dopados n.

2.&n= bsp;      La fotoconductividad de estado estaciona= rio bajo una tasa de generación uniforme modulada en el tiempo (MPC), para un r= ango de temperaturas estimado entre  y , existen valores de fotoconducción significativos, sin embargo, los modelos teóricos y experimentales son consistentes sólo para valores de temperatura .

3.&n= bsp;     Para la técnica basada en el patr= ón de interferencia estacionario (SSPG), se consigue foto= conducción muy baja, los modelos son consistentes sólo cuando los coeficientes de conductividad son iguales en todas las regiones.

4.&n= bsp;     Con la técnica del patrón de interferencia móvil (MGT), se consigue buena estimulación a la formación de fotocorrientes para altos valores de frecuencia, temperatura, e intensidad = de luz. Los modelos con consistentes para tasas de temperatura y generación de portadores uniformes.

5.&n= bsp;     La técnica del patrón de interferencia modulado en el tiempo (MPG), muestra que, para frecuencias al= tas, campos eléctricos muy bajos, y periodos grandes, se genera buena fotoconducción en el material. Los modelos sólo son consistentes bajo estas condiciones.

6.&n= bsp;     El patró= n de interferencia vibrante (VPG), para bajas frecuencias, aparece muy buena= fotoconducción en el material, sin embargo, los model= os son consistente bajo suposiciones teóricas muy aproximadas, incluso, algunas ve= ces erradas.

7.&n= bsp;     El uso de la técnica del patrón de interferencia oscilante (OPG), muestra = que los modelos son consistentes, considerando la suposición de que la diferenc= ia de potencial aplicada induce un cambio de fase en la luz polarizada sólo en= sus direcciones principales

8.&n= bsp;     La técnica referida al uso de simulaciones computacionales, a través de métodos numéricos como: Monte Car= los, Runge-Kutta, y elementos finitos, proporciona b= uenos resultados que son consistentes tanto con el modelo teórico como con los resultados experimentales. Estos son más aproximados cuando se contrastan c= on los arrojados por MGT, OPG, y CMG.

En lo que respecta a los polímeros, además, de evidenciarse aumento en la fotoconductividad, por medio de la técnica expue= sta, se ha logrado, la síntesis y purificación de los copolímeros usando AIBN. Este compuesto orgánico = está formado por aminoisobutironitrilos unidos entre= sí por un enlace  , por lo que se considera un azoderivado= , que a temperatura ambiente se presenta como un sólido, en forma de cristales columnados de color blanco. También puede encontrarse en forma de polvo. Además, se logró su caracterización, usando cromatografía de tamańos con ín= dice de refracción, y difusión de la luz a múltiples ángulos. =

Sobre el comportamiento fotof= ísico de los copolímeros, se pudo estudiar la formación de excímeros intramolecul= ares y transferencia de energía, con el uso de la fluorescencia en estados estacionarios transitorios, reportándose espectros de emisión de todos los compuestos usados como muestra material, además, de los estados de vida excitados, y los espectros de anisotropía.

Estas medidas permitieron hacer una caracterizació= n de los excímeros con respecto a su fotoconducción, además, de obtener información sobre procesos de formación, y eficiencia en= la transferencia de energía intramolecular, que son magnitudes íntimamente relacionadas con la capacidad para conducir que presentan estos materiales.=

En la caracterización de cristales, a través de la técnica de generación de fotocorriente provocada por patrones de iluminación dinámicos (photo-EMF), los resultados experimen= tales presentados por el autor, presentan cambios favorables en el fotoconductor hacia la conducción de portadores, cuando el material se encuentra en prese= ncia de un campo eléctrico uniforme, externo y fuerte, lo cual se puede apreciar= en el aumento paulatino de las vibraciones en un alto rango, sin necesidad de = usar el mecanismos proporcionado por la técnica photo-EMF.

En cuanto al método numérico empleado (aproximacio= nes numéricas Runge-Kutta), se encontró que los mod= elos obtenidos permiten la descripción del transporte y captura de cargas en el fotoconductor, muy aproximadas a los resultados experimentales, y analítico= s. Además, los resultados obtenidos por la vía de la simulación, muestran que = la producción de fotocorriente alterna, posiblemente, se deba a la asimetría d= el campo interno.

Dentro de las posibles aplicaciones de las técnica= s, lo más notable se menciona a continuación.

1.&n= bsp;     SPV ha encontrado gran aplicabili= dad en la microscopía de potencia de superficie, y la producción de mapas de lí= neas equifotovoltaicas. 

2.&n= bsp;     La recombinación dependiente de g= iro, con valores de G medios y cambios de conductividad, permite la obtención de información significativa y detallada para describir las vías de conducción asociadas con el spín, además, de aplicaciones a celdas solares y diodos LED.

3.&n= bsp;     TRMC, posee la virtud de que se p= uede llevar a cabo sin contacto con el material, lo que ha conllevado a aplicaci= ones para el estudio de muestras con grandes superficies, las cuales son fundamentales en la fotocatálisis. También se pueden encontrar aplicaciones= en células solares, y sensibilidad de colorantes para industria química. =

4.&n= bsp;     PPC, ha permitido que se puedan h= acer caracterizaciones de materiales, aumentando la clasificación de los semiconductores, lo cual ha repercutido de manera relevante en las aplicaci= ones optoelectrónicas, los dispositivos regradables,= y los fotodetectores.

5.&n= bsp;     IR, usa espectroscopia electrónic= a, para la identificación de especies químicas, concentración de los compuesto= s, y comparación de los espectros para hacer comparación de propiedades en las muestras.

6.&n= bsp;     La espectroscopia UV-VIS, tiene importantes aplicaciones en los fenómenos en donde la fluorescencia es una propiedad característica importante. Sin embargo, estos métodos se aplican menos que los de absorción, descansando este hecho en que pocos materiales = son capaces de fluorescer.

 

Conclusiones.

ˇ      =    La técnicas basadas en la aplicación = de patrones de interferencia en estado estacionario y transitorio= (SSPC, MPC, SSPG, MGT, MPG, VPG, y OPG), reportan consistencia con los resultados<= /span> analíticos y simulados, <= span class=3DSpellE>permitiendo tanto la caracterización de materiales como aumentos en la fotoconducc= ión de los mismos, sin = embargo, los resultados más = aproximados y más promisorios en cuanto al = aumento de fotocorrientes= en el material, resultaron corre= sponder con la técnica VPG, la cua= l se recomienda ampliamente<= /span> para estados extendidos, en donde se asume el m= odelo de captura y emisión múltiple de portadores (bastante común en muchos materiales usados en la ingeniería e industria). Esta técnica, = permite la creación y caracterizac= ión de nuevos materiales, entre ellos, los excímeros y copolímeros, de aplicaciones muy útiles y de bajo costo.   

ˇ      =    Otras técnicas revisadas, SPV, ofrece ventajas en los materiales a granel, y desventajas en películas delgadas, pero es potencialmente aplicable en la separación de materiales y la caracterización de puntos cuánticos. Si se compara SPV, con las técnicas basadas en la aplicación de patrones de interferencia estacionarios y transitorios, y TRMC, las segundas presentan desventajas, pues necesitan obligatoriamente del uso de puntas de contacto = material, lo cual no permite trabajar con polvos, agregados de materiales nanoporosos= , y otras sustancias en las cuales es imposible definir electrodos.<= /span>

ˇ         Todas las técnicas anteriores, so= n de difícil aplicación en el diseńo y construcción de células solares, disposit= ivos regrabables y fotodectores, dados sus estados materiales, por lo que se recomiendan las técnicas PPC, dado que, resultan poseer altas propiedades optoelectrónicas, lo cual abarata costos de diseńo= y fabricación. Sin embargo, técnicas de menores costos y mayor versatilidad experimental, están relacionadas con la IR, las cuales resultan ser sencill= as de preparar, además, de que se obtienen resultados más rápidos y sensibles = para analizar. La desventaja que presentan, es que no son aplicables a materiales monoatómicos, ni a moléculas con la misma característica, pues los átomos q= ue las conforman se hacen indistinguibles.  <= /span>

ˇ      =    Las técnicas de simulación computacional, dada su versatilidad y potencial, a través de los distintos softwares disponibles en la actualidad, y de la consistencia de los modelos simulados con los resultados analíticos y experimentales en el campo de la = fotoconducción, pueden sustituir, con poca inversión monetaria, en todos los niveles, y en el ciclo de vida completo, el producto generado por la costosa experimentación.

ˇ      =    En la actualidad, no hay un entendimiento real de cómo funcionan esta mezcla de materiales, por la falta de modelos analíticos y experimentales aproximados. Esto podría ser solucionado a través de una simulación, o de la aplicación = de algoritmos de aprendizaje, sin recurrir a una costosa prueba de laboratorio= . La desventaja de estos métodos numéricos, está relacionada con el coste computacional, pues el proceso de modelado requiere de la elaboración de sofisticadas de mallas de elementos, las cuales, en ciertos casos, pueden s= er de ordenes de magnitud muy grandes, provocando excesos de procesamiento de datos en el computador y posibles riesgos de dańos irreversibles.

 

Referencias bibliográficas.

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Ko, T. S., Chen, Z. W., Lin, D. Y= ., Suh, J., & Chen, Z. S. (2017). Observation of persistent photoconductivity in Ni-doped MoS2. Japanese Journal of Applied Physics<= /i>, 56(4). https://doi.org/= 10.7567/JJAP.56.04CP09.

Kronik, L., & Shapira, Y. (19= 99). Surface photovoltage phenomena: theory, experiment, and applications. Tel Avid: Universtity Tel-Avid. Department of Physical Electronics.

Koprio, L. (2019). = Desarrollo y optimización de técn= icas basadas en la fotoconductividad para la caracterización de semiconductores = con aplicaciones fotovoltaicas.  Santiago: Universidad Nacional del Lito= ral. Grupo de Física de Semiconductores.

Lee, G., Mun, B., Today, H. J.-A.= M., & 2021, U. (2021). Observation of giant persistent photoconductivity on vanadium dioxide thin film device. Elsevier. https://www.scie= ncedirect.com/science/article/pii/S2352940720303425.

Peńa N. (2011). Caracterización de polímeros fotoconductores mediante cromatografía con detección múltiple, técnicas de fluorescencia y mecánica y dinámica molecular= . Alacalá: Universidad de Alcalá. Departamento de Química Física.

Pillai, S., Anderson, N., Wang, C= ., Bjuggren, J., & Jevric, M. (2019). Validation of Time-Resolved Micro= wave Conductivity (TRMC) as a screening tool for all-polymer solar cells<= /i>. https://bridges.monash.edu/articles/Validation_of_Time= Resolved_Microwave_Conductivity_TRMC_as_a_screening_tool_for_all-polymer_so= lar_cells/8313068.

Savenije, T., Thieme, J., & W= ei, Z. (2020). Using Time-Resolved Photoconductivity Measurements to Reveal the Urbach Tail and Two Photon Absorption in MHPs. Hal.Archives-Ouvertes.Fr<= /i>. https://hal.arch= ives-ouvertes.fr/hal-03030584/.

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Vega, A. (2019). Fuerza foto-electromotriz en películas de perovskita. Puebla: Instituto Nacion= al de Astrofísica, Óptica y Electrónica. Insituto de Óptica Aplicada.

 

 

 

 

 

PARA CITAR EL ARTÍCULO INDEXADO.

 

 

Arambulo Almendariz, C. D., & Carrera Almendáriz, L.= S. (2021). Técnicas experimentales para caracterizar materiales fotoconductore= s. ConcienciaDigital, 4(3), 196-210. https://doi.org/10.33262/concienciadigital.v4i3.1793

 

 


El artículo que se publica es de exclusiva responsabilidad de los autores y no necesariamente reflejan el pensamiento de la Revista Concienc= ia Digital.

 

El artículo qu= eda en propiedad de la revista y, por tanto, su publicación parcial y/o total en otro medio tiene que ser autorizado por el director de la Revista Conciencia Digital.

 

                                                 =                                                                            =                       

 

 



[1] Escuela Superior Politécnica= de Chimborazo Facultad de Ciencias, Riobamba, Ecuador, cristian.arambulo@espoc= h.edu.ec ORCID: 0000-0003-19= 15-0976

[2] Escuela Superior Politécnica= de Chimborazo, Facultad de Ciencias, Riobamba, Ecuador, luissantiago.carrera@e= spoch.edu.ec ORCID: 0000-0002-3262-5895=

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www.concienciadigital.org

                                                 =                                                                       ISSN: 2600-5859

                                                   =                Vol. 4, N°3, p. 196-210, julio - septiembre, 20 21

Mundo en Pandemia                                                =                                                         =                              Página 177=

 

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